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Stereoselective Glycosylations by Nitrosyl Tetrafluoroborate-Catalyzed Activation of Glycosyl Trichloroacetimidate Derivatives

  作者 SAU ABHIJIT; SANTRA ABHISHEK; MISRA ANUP KUMAR  
  选自 期刊  SYNLETT;  卷期  2012年-16;  页码  2341-2348  
  关联知识点  
 

[摘要]Efficient stereoselective glycosylation conditions have been developed by using nitrosyl tetrafluoroborate (NOBF4) promoted activation of glycosyl trichloroacetimidate derivatives. A series of mono- and disaccharide derivatives were synthesized in excellent yield, and high stereoselectivity at the glycosylation center was observed in every case.

 
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