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Directed nucleation of monomeric and dimeric uranium(VI) complexes with a room temperature carboxyl-functionalized phosphonium ionic liquid

  作者 CHEN XIAOYAN; GOFF GEORGE S; QUIROZGUZMAN MAURICIO; FAGNANT DANIEL P JR; BRENNECKE JOAN F; SCOTT BRIAN L; RUNDE WOLFGANG  
  选自 期刊  Chemical Communications;  卷期  2013年49-19;  页码  1903-1905  
  关联知识点  
 

[摘要]The carboxyl-functionalized phosphonium ionic liquid (IL), [HCTMP]-[Tf2N], enabled the directed nucleation of monomeric or dimeric uranyl(VI) compounds. This new IL is the first carboxyl-functionalized IL which is liquid at room temperature and exhibits a wider electro-chemical window and lower melting point than its ammonium analogue.

 
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