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[摘要]:High-performance n-type organic field-effect transistors (OFETs) based on 2-dimensional (2D) crystalline layered films of the novel dicyanodistyrylbenzene (DCS) derivative (2Z,2'Z)-3,3'-(1,4-phenylene)bis(2-(3,5-bis(trifluoromethyl)phenyl)acrylonitrile) (CN-TFPA) were fabricated using a simple solution process. The OFETs showed electron mobilities of up to 0.55 cm(2) V-1 s(-1), which was attributed to the appropriate electron affinity and dense molecular packing in the well-ordered 2D terrace structure. Because of the easy exfoliation capabilities of the CN-TFPA 2D crystalline layers, 2-10 CN-TFPA molecular monolayers could be successfully transferred onto the substrates, enabling the fabrication of ultrathin OFET devices with an active layer thickness of similar to 30 nm. |
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