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C-C Bond-Forming Click Synthesis of Rotaxanes Exploiting Nitrile N-Oxide

  作者 MATSUMURA TOHRU; ISHIWARI FUMITAKA; KOYAMA YASUHITO; TAKATA TOSHIKAZU  
  选自 期刊  Organic Letters;  卷期  2010年12-17;  页码  3828-3831  
  关联知识点  
 

[摘要]A click end-capping reaction exploiting nitrile N-oxide to rotaxane was described with emphasis of productivity of the protocol via stable C C bond formation. Establishment of a pH-driven molecular shuttling system was also demonstrated by practical neutralization of the sec-ammonium group of the rotaxane axle with potassium hydroxide.

 
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