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Pd-Catalyzed Carbonylative Conjugate Addition of Dialkylzinc Reagents to Unsaturated Carbonyls

  作者 CUSTAR DANIEL W; LE HAI; MORKEN JAMES P  
  选自 期刊  Organic Letters;  卷期  2010年12-17;  页码  3760-3763  
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[摘要]The Pd-catalyzed addition of organozinc reagents to unsaturated carbonyls in the presence of carbon monoxide provides 1,4-diketones in good yield. The reaction was studied with a number of substituted cyclic and acyclic ketones as well as alpha,beta-unsaturated aldehydes.

 
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