Evaluation of Amino Acids as Chiral Ligands for the Enantiodifferentiation of Carbohydrates by TOCSY NMR

[摘要]：The use of natural amino acids as chiral ligands on a triethylbenzene scaffold for the binding and enantiodifferentiation of carbohydrates has resulted in moderate affinity and selectivity values for glucose. Selective I D TOCSY experiments revealed this as a powerful titration technology surpassing the severe overlapping of receptor and carbohydrate signals in H-1 NMR spectra.

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