Tributyltin Hydride as a Selective Reducing Agent for Aryl Enones

[摘要]：Aryl enones undergo selective 1,4-reduction to the corresponding saturated ketones with two equivalents of tributyltin hydride in the presence of a wide range of other potentially reducible functional groups, including alkyl enone. Additionally during this investigation reductive cyclization of bisenones to give five-and six-membered carbocycles via an alpha, beta-coupling process was observed.

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