1,8-Hydrogen Atom Transfer Promoted by N-Radicals in (1?4)-O-Disaccharide Models

[摘要]：The nitrogen-centered radical generated by reaction of an N-sulfonamidate, attached to C-6 of a hexopyranose in a disaccharide model, with (diacetoxyiodo)benzene (DIB) andiodine undergoes a novel regio- and stereoselective intramolecular 1,8-hydrogen atom transfer (HAT) reaction to promote the functionalization of remote positions.

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