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Visible-Light-Mediated alpha-Arylation of Enol Acetates Using Aryl Diazonium Salts

  作者 HERING THEA; HARI DURGA PRASAD; KOENIG BURKHARD  
  选自 期刊  Journal of Organic Chemistry;  卷期  2012年77-22;  页码  10347-10352  
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[摘要]Visible light mediates efficiently the alpha-arylation of enol acetates by aryl diazonium salts under mild conditions using [Ru(bpy)(3)]-Cl-2 as a photoredox catalyst. The broad scope of the reaction toward various diazonium salts and enol acetates was explored. The application of this reaction in the concise synthesis of 2-substituted indoles was demonstrated

 
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