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Methylenecyclopropanes in [4+1] Cycloaddition with Enones

  作者 INAMI TASUKU; SAKO SAORI; KURAHASHI TAKUYA; MATSUBARA SEIJIRO  
  选自 期刊  Organic Letters;  卷期  2011年13-15;  页码  3837-3839  
  关联知识点  
 

[摘要]A nickel-catalyzed [4 + 1] cycloaddition of enones with methylenecyclopropanes leading to dihydrofurans was developed. The reaction outcome is attributed to the transformation of methlenecyclopropane, which is incorporated Into a five-membered ring as a one-carbon fragment.

 
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