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[摘要]:An efficient stereoselective total synthesis of (+)-(4S,5S)-muricatacin was accomplished in good yields from inexpensive, commercially available chemicals ((+)-diethyl tartrate (DET) and undecan-1-ol) by utilizing Mitsunobu and Julia-Kocienski reactions, Wittig homologation, Swern oxidation, and lactonization. |
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