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Stereoselective Synthesis of Novel N-beta-Glycosyl Sulfonamides by Sulfonamidoglycosylation of Per-O-acetylated Sugars

  作者 ALFONSO COLINAS PEDRO; AGUSTIN TEMPERA CARLOS; MARIANO RODRIGUEZ OSCAR; DANIEL BRAVO RODOLFO  
  选自 期刊  Synthesis;  卷期  2009年-24;  页码  4143-4148  
  关联知识点  
 

[摘要]A series of novel N-glycosyl sulfonamides is prepared by sulfonamidoglycosylation of per-O-acetylated sugars. The products which contain an unnatural sulfonamide moiety at the anomeric centre are obtained in very good yields and with excellent beta-stereoselectivity, even with per-O-acetylated D-mannose.

 
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