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Nickel-Catalyzed Hydrosilylation/Cyclization of Difluoro-Substituted 1,6-Enynes

  作者 TAKACHI MANABU; CHATANI NAOTO  
  选自 期刊  Organic Letters;  卷期  2010年12-22;  页码  5132-5134  
  关联知识点  
 

[摘要]Ni-catalyzed hydrosilylative cyclization of difluoro-substituted 1,6-enynes can be carried out. The presence of a geminal-difluoromethylene group at an alkene terminus in enynes is essential for the reaction to proceed.

 
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