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CONVERSION OF TWO EREMOPHILANE GLUCOSIDES FROM PITTOCAULON PRAECOX INTO EREMOPHILANOLIDES

  作者 ARCINIEGAS AMIRA; IRONZI MALDONADO JHON; PEREZCASTORENA ANAL; ROMO DE VIVAR ALFONSO  
  选自 期刊  Heterocycles;  卷期  2012年85-11;  页码  2735-2744  
  关联知识点  
 

[摘要]Two eremophilanolides (3, 4), an aldehyde (6), an intramolecular addition product (7), and two water addition products (8, 9) were obtained by acid treatment of the eremophilane glucosides 10 and 11. A reaction mechanism supported by deuterium labeling is proposed for the conversion of eremophilane glycosides into eremophilanolides.

 
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