Total Synthesis of (-)-Delta(8)-trans-Tetrahydrocannabinol

[摘要]：(-)-Delta(8)-trans-Tetrahydrocannabinol was synthesized with high regio- and stereoselectivity through S(N)2' addition of an arylcyanocuprate to the optically pure enol silyl ether of alpha,beta-epoxy-cyclohexanone.

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