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Pressure-induced changes in the dielectric response of polymer relaxors - art. no. 052904

  作者 Hilczer, B; Szafranski, M; Hilczer, A  
  选自 期刊  Applied Physics Letters;  卷期  2012年100-5;  页码  52904-52904  
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[摘要]The effect of hydrostatic pressure on the dielectric response of P(VDF/TrFE)(50/50) irradiated with fast electrons has been studied. A non-linear upward shift of the glass transition temperature T-g and the Curie temperature T-C of the polymer relaxors was observed under pressure with the initial slope dT(g)/dp being considerably smaller than dT(C)/dp. Moreover, pressure was found to reduce the contribution to the low-frequency dielectric absorption originating from segmental motions in the amorphous phase whereas the contribution related to ferroelectric-paraelectric transition and that of polar nanoclusters in the crystalline phase were found to be enhanced. (C) 2012 American Institute of Physics. [doi:10.1063/1.3681372]

 
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