Synthesis of enamides via Rh/C-catalyzed direct hydroacylation of ketoximes.

[摘要]：Enamides were efficiently prepd. via a novel Rh/C-catalyzed direct hydroacylation of ketoximes. Up to 88% isolated yield of enamides were obtained with this method. Subsequent asym. hydrogenation of the enamides with Rh/DuanPhos complex gave the corresponding chiral amine in excellent enantioselectivities (up to 99.7% ee).

[全文传递流程]：

一般上传文献全文的时限在1个工作日内