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Syntheses of trans-SCH-A and cis-SCH-A via a Stereodivergent Cyclopropanation Protocol

  作者 CSATAYOVA KRISTINA; DAVIES STEPHEN G; LEE JAMES A; LING KENNETH B; ROBERTS PAUL M; RUSSELL ANGELA J; THOMSON JAMES E  
  选自 期刊  Organic Letters;  卷期  2010年12-14;  页码  3152-3155  
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[摘要]A highly diastereoselective cyclopropanation protocol has been employed in the syntheses of trans-SCH-A and cis-SCH-A. This strategy encompasses a stereodivergent procedure for the preparation of syn- and anti-cyclopropane diastereoisomers in high dr from a common allylic carbamate precursor.

 
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