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Highly active ammonium-tagged olefin-metathesis catalyst for simplified purification.

  作者 Kirschning, Andreas;Gulajski, Lukasz;Mennecke, Klaas;Meyer, Axel;Busch, Torsten;Grela, Karol;  
  选自 期刊  SYNLETT;  卷期  2008年-17;  页码  2692-2696  
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[摘要]When an 2-isopropoxy-substituted benzylidene ligand of a Hoveyda-type Ru-metathesis complex is modified by an addnl. 4-diethylamino group and treated with PTSA it yields a highly active precatalyst suitable for RCM, cross metathesis, and enyne metathesis. The important property of this ammonium tagged Ru-complex is assocd. with the possibility of its easy removal by a simple filtration protocol.

 
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