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UV-visible-light-activated photocatalysts based on Bi2O3/Bi4Ti3O12/TiO2 double-heterostructured TiO2 nanobelts

  作者 ZHAO ZHENHUAN; TIAN JIAN; WANG DONGZHOU; KANG XUELIANG; SANG YUANHUA; LIU HONG; WANG JIYANG; CHEN SHAOWEI; BOUGHTON ROBERT I; JIANG HUAIDONG  
  选自 期刊  Journal of Materials Chemistry;  卷期  2012年22-44;  页码  23395-23403  
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[摘要]Surface engineering of TiO2 nanobelts by the controlled assembly of functional heterostructures represents an effective approach for the synthesis of high-performance photocatalysts. In this study, we prepared a novel Bi2O3/Bi4Ti3O12/TiO2 double-heterostructured nanobelt by depositing bismuth hydroxide onto the TiO2 nanobelt surface. A thermal annealing treatment led to the formation of a Bi4Ti3O12 interlayer that functioned as a bridge to link Bi2O3 and TiO2. The double-heterostructured TiO2 nanobelts exhibited better UV light photocatalytic performance than commercial P25. Importantly, the photocatalytic activity in the visible range was markedly better than that of Bi2O3 and Bi2O3/TiO2 heterostructured TiO2 nanobelts. The enhanced performance was accounted for by the material band structures where the matching was improved by the unique interlayer.

 
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