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Reinvestigation of Aminomethyltrifluoroborates and Their Application in Suzuki-Miyaura Cross-Coupling Reactions

  作者 RAUSHEL JESSICA; SANDROCK DEIDRE L; JOSYULA KANTH V; PAKYZ DEBORAH; MOLANDER GARY A  
  选自 期刊  Journal of Organic Chemistry;  卷期  2011年76-8;  页码  2762-2769  
  关联知识点  
 

[摘要]A reinvestigation into the chemical composition of potassium aminomethyltrifluoroborates is reported. These trifluoroborato salts have been reassigned as zwitterionic ammoniomethyltrifluoroborates. Minor adjustments to the previously disclosed reaction conditions are reported that permit a similar level of activity as nucleophiles in Suzuki-Miyaura cross-coupling reactions.

 
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