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Synthesis of 3-Substituted Isocoumarin Derivatives via CuI-Catalyzed Reaction of o-Bromobenzamides with 1,3-Diketones

  作者 CAI SHANGJUN; WANG FEI; XI CHANJUAN  
  选自 期刊  Synthesis;  卷期  2012年44-12;  页码  1892-1897  
  关联知识点  
 

[摘要]An approach to a variety of 3-substituted isocoumarins has been developed. The reaction proceeded from o-bromobenzamide derivatives and 1,3-diketones via CuI-catalyzed reaction in DMF under the action of K3PO4 at 120 degrees C without ligands or additives.

 
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