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Cu(OTf)2-catalyzed isomerization of 7-oxabicyclic alkenes: a practical route to the synthesis of 1-naphthol derivatives.

  作者 Peng, Fangzhi;Fan, Baomin;Shao, Zhihui;Pu, Xuewei;Li, Penghui;Zhang, Hongbin;  
  选自 期刊  Synthesis;  卷期  2008年-19;  页码  3043-3046  
  关联知识点  
 

[摘要]Lewis acid catalyzed isomerization of 7-oxabicyclic alkenes into 1-naphthol derivs., e.g., I, in high yields (87-98%) under mild reaction conditions has been developed. The mechanism of this reaction is briefly postulated.

 
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