Cu(OTf)2-catalyzed isomerization of 7-oxabicyclic alkenes: a practical route to the synthesis of 1-naphthol derivatives.
[摘要]:Lewis acid catalyzed isomerization of 7-oxabicyclic alkenes into 1-naphthol derivs., e.g., I, in high yields (87-98%) under mild reaction conditions has been developed. The mechanism of this reaction is briefly postulated.
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