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Domino Twofold Heck/6 pi-Electrocyclization Reactions of 1,2-Dihaloalkenes

  作者 HUSSAIN MUNAWAR; TRAN VAN SUNG; LANGER PETER  
  选自 期刊  SYNLETT;  卷期  2012年-19;  页码  2735-2744  
  关联知识点  
 

[摘要]Domino twofold Heck/6 pi-electrocyclization reactions of 1,2-dihaloalkenes allow for a convenient synthesis of benzene derivatives. In recent years, this strategy has been applied to various 1,2-dihalogenated carbocyclic alkenes and heterocycles, and a variety of benzo-fused ring systems have been prepared. The electrocyclization reactions proceed well for five-membered, but not for six-membered heterocycles.

 
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