Synthesis of novel bicyclic nitroxides using partial Favorskii rearrangement.

[摘要]：3-Bromo-2,2,6,6-tetramethyl-4-oxopiperidine-1-oxyl (I) was reacted with several C-nucleophiles to give novel bicyclic pyrrolidine nitroxides through partial Favorskii rearrangement. Further redn. with sodium borohydride gave spin probes with free hydroxyl groups and under harsh redn. conditions allowed the Favorskii rearrangement to proceed to completion.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内