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Gold-Catalyzed Skeletal Rearrangement of 1-[2-(1H-Isochromen-3-yl)aryl]ethanones with Alcohols

  作者 WEI WENTING; XIE PENG; XIA JIADONG; XIE YEXIANG; SONG RENJIE; XIANG JIANNAN; LI JINHENG  
  选自 期刊  Synthesis;  卷期  2012年44-13;  页码  2049-2057  
  关联知识点  
 

[摘要]A novel gold-catalyzed skeletal rearrangement of 1-[2-(1H-isochromen-3-yl)aryl]ethanones with alcohols to construct a five-membered carbocycle ring onto aromatic systems has been developed. This method serves as the first example of synthesizing inden-1-ones by a gold-catalyzed skeletal rearrangement strategy.

 
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