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DEVELOPMENT OF CYCLIC HYDRAZINE AND HYDRAZIDE TYPE ORGANOCATALYST-MECHANISTIC ASPECTS OF CYCLIC HYDRAZINE/HYDRAZIDE-CATALYZED DIELS-ALDER REACTIONS

  作者 SUZUKI ICHIRO; HIRATA AI; TAKEDA KEI  
  选自 期刊  Heterocycles;  卷期  2009年79-1;  页码  851-863  
  关联知识点  
 

[摘要]Some hydrazines and hydrazides were prepared and screened for their catalytic efficiencies in Diets-Alder reactions. H-1-NMR studies and ab initio calculations revealed that catalytic efficiencies of these catalysts are greatly dependent on the release of the catalysts from the Diels-Alder adducts.

 
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