Synthesis of C13-C23 Fragment of Iriomoteolide-1a

[摘要]：Highly efficient asymmetric conjogate addition of MeMgBr to alpha,beta-unsaturated esters catalyzed by Cul/Tol-BINAP, Paterson aldol, organocatalytic aldol, and cross-metathesis reactions were applied in the synthesis of C13-C23 fragment of Iriomoteolide-1a.

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