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[摘要]：Nitrogen-enriched nonporous carbon materials derived from melamine-mica composites are subjected to ammonia treatment to further increase the nitrogen content. For samples preoxidized prior to the ammonia treatment, the nitrogen content is doubled and is mainly incorporated in pyrol-like groups. The materials are tested as electrodes for supercapacitors, and in acidic or basic electrolytes, the gravimetric capacitance of treat samples is three times higher than that of untreated samples. This represents a tenfold increase of the capacitance per surface area (3300 mu F cm(-2)) in basic electrolyte. Due to the small volume of the carbon materials, high volumetric capacitances are achieved in various electrolytic systems: 280 F cm(-3) in KOH, 152 F CM-3 in H2SO4, and 92 F cm(-3) in tetraethylammonium tetrafluoroborate/propylene carbonate. |
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