STUDIES TOWARD INTRAMOLECULAR CYCLOADDITION OF o-QUINODIMETHANE WITH AN OXAZOLE MOIETY

[摘要]：Thermal reaction of benzocyclobutene derivatives having an oxazole moiety was investigated. Intramolecular [4+2] cycloaddition of o-quinodimethane, generated by thermolysis of the benzocyclobutene, with the oxazole did not proceed, and instead, [1,5]-sigmatropic rearrangement occurred dominantly.

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