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Benzothiadiazoloperylenes and Benzoxadiazoloperylenes: Amorphous Functional Materials

  作者 LANGHALS HEINZ; KNOCHEL PAUL; WALTER ANDREAS; ZIMDARS SILVIA  
  选自 期刊  Synthesis;  卷期  2012年44-22;  页码  3465-3476  
  关联知识点  
 

[摘要]2,1,3-Benzothiadiazole or 2,1,3-benzoxadiazole were magnesiated (TMP2Mg center dot 2LiCl) and efficiently attached to perylene and benzoperylene building blocks providing amorphous light-absorbing materials where FRET energy transfer proceeds between the 2,1,3-benzothiadiazole or 2,1,3-benzoxadiazole and the perylene units. Some of these new materials were obtained as amorphous solids of interest for material science.

 
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