Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts
[摘要]:[Pd(NHC)(PR3)] complexes were shown to be active catalysts in the dehydrogenation of ammonia borane and the subsequent hydrogenation of unsaturated compounds at very low catalyst loadings (0.05 mol% for some substrates).
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