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Spontaneous Phase Separation Mediated Synthesis of 3D Mesoporous Carbon with Controllable Cage and Window Size

  作者 Lee, HI; Stucky, GD; Kim, JH; Pak, C; Chang, H; Kim, JM  
  选自 期刊  ADVANCED MATERIALS;  卷期  2011年23-20;  页码  2357-2357  
  关联知识点  
 

[摘要]Colloidal silica templated mesoporous carbons, which not only have a systematically expanded large cage size (5-45 nm) but also controlled window size (5-25 nm), are successfully obtained via spontaneous phase separation of boron species from mixture of carbon precursor, boric acid, and colloidal silica during carbonization process. This novel synthesis offers a new chance to control the pore structure in materials obtained by nanoreplication using rigid templates.

 
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