Controlling Enantioselectivity in Additions to Cyclic Oxocarbenium Ions via Transition-Metal Catalysis

[摘要]：Controlling enantioselectivity in additions to oxocarbenium ions remains a challenge in asymmetric catalysis. By using a catalytically generated chiral organometallic intermediate, a copper acetylide, we have developed a novel approach for additions of carbon nucleophiles to cyclic oxocarbenium ions in high enantioselectivities and yields.

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