Copper-Catalyzed Remote sp(3) C-H Chlorination of Alkyl Hydroperoxides

[摘要]：A copper-catalyzed methodology to functionalize remote sp(3) C-H bonds in alkyl hydroperoxides is presented. The atom-transfer chlorination utilizes simple ammonium chloride salts as the chlorine source, and the internal redox process requires no external redox reagents.

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