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Efficient Diacetoxylation of Alkenes via Pd(II)/Pd(IV) Process with Peracetic Acid and Acetic Anhydride

  作者 PARK CHAN PIL; LEE JOO HO; YOO KYUNG SOO; JUNG KYUNG WOON  
  选自 期刊  Organic Letters;  卷期  2010年12-11;  页码  2450-2452  
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[摘要]A palladium-catalyzed diacetoxylation of alkenes in the presence of peracetic acid and acetic anhydride was developed to produce diacetates efficiently and diastereoselectively. Due to its mild conditions, this method was suitable for a broad range of substrates encompassing conjugated and nonconjugated olefins.

 
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