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Reusable Visible Light Photoredox Catalysts; Catalyzed Benzylic C(sp(3))-H Functionalization/Carbocyclization Reactions

  作者 XIA JIADONG; DENG GUOBO; ZHOU MINGBO; LIU WEI; XIE PENG; LI JINHENG  
  选自 期刊  SYNLETT;  卷期  2012年-18;  页码  2707-2713  
  关联知识点  
 

[摘要]The C(sp(3))-H functionalization/carbocyclization reaction through the oxidative quenching of visible light photoredox catalysts is established for constructing functionalized 1H-indenes. The process is general for a wide range of benzylic C(sp(3))-H bonds and is highly compatible with common functional groups. Importantly, the visible light photoredox catalysts can be recovered and reused at least three times without loss of catalytic activity.

 
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