A new class of highly solvatochromic dicyano rhenate(I) diimine complexes - synthesis, photophysics and photocatalysis

[摘要]：A new class of dicarbonyl dicyano rhenate(I) diimine complexes, cis,trans-[Re(CO)(2)(CN)(2)(N-N)](-), with highly environmentally sensitive MLCT absorption and emission properties was synthesised and characterised. Preliminary experiments revealed that these complexes are active photocatalysts for CO2 reduction.

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