Asymmetric Synthesis of 6'-Hydroxyarenarol: The Proposed Biosynthetic Precursor to Popolohuanone E.

[摘要]：The first synthesis of (+)-6'-hydroxyarenarol (I), the proposed biogenetic precursor to popolohuanone E, is described. An enantioselective route to a key iodide intermediate has been developed allowing the asym. synthesis of a known cis-decalin. Conditions which allow the removal of the Me ether protecting groups on the hydroxyarene leaving the exocyclic methylene moiety in tact have also been developed to complete this synthesis.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内