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Aerobic Photooxidative Cleavage of Vicinal Diols to Carboxylic Acids Using 2-Chloroanthraquinone

  作者 MATSUSAKI YOKO; YAMAGUCHI TOMOAKI; TADA NORIHIRO; MIURA TSUYOSHI; ITOH AKICHIKA  
  选自 期刊  SYNLETT;  卷期  2012年-14;  页码  2059-2062  
  关联知识点  
 

[摘要]We developed the aerobic photooxidative cleavage of vicinal diols to carboxylic acids using 2-chloroanthraquinone in the presence of photoirradiation with a high-pressure mercury lamp. This is the first metal-free reaction using molecular oxygen as the terminal oxidant.

 
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