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Synthetic Studies on CP-225,917 and CP-263,114: Access to Advanced Tetracyclic Systems by Intramolecular Conjugate Displacement and [2,3]-Wittig Rearrangement

  作者 MALIHI FARZAD; CLIVE DERRICK L J; CHANG CHECHIEN; MINARUZZAMAN  
  选自 期刊  Journal of Organic Chemistry;  卷期  2013年78-3;  页码  996-1013  
  关联知识点  
 

[摘要]An advanced intermediate related to the structures of CP-225,917 and CP-263,114 was constructed by a sequence based on R the use of Grob-like fragmentation, intramolecular conjugate displacement, and [2,3]-Wittig rearrangement. A variant of the [2,3]-Wittig rearrangement was developed.

 
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