Bronsted Acid Catalyzed Asymmetric Aldol Reaction: A Complementary Approach to Enamine Catalysis

[摘要]：A syn-enantioselective aldol reaction has been developed using Bronsted acid catalysis based on H-8-BINOL-derived phosphoric acids. This method affords an efficient synthesis of various beta-hydroxy ketones, some of which could not be synthesized using enamine organocatalysis.

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