[摘要]:We have applied x-ray magnetic circular dichroism to investigate the field-induced ferromagnetism in Pd40Ni22.5Fe17.5P20 alloy. The experiment revealed that both Ni and Fe were in a divalent state and that the magnetic properties of the material were determined by the localized 3d electrons of the transition metals. No clear evidence of Ruderman-Kittel-Kasuya-Yosida-type interaction among magnetic clusters was observed. It is believed that the detailed balance of fundamental spin-orbit and exchange interactions as a function of temperature and applied magnetic field determine the different magnetic properties of the alloy.