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[摘要]：Synthesis and characterization of a new type of Lewis acid, rare earth metal perfluorooctanoate, as well as the recent development of multicomponent condensation reactions catalyzed by rare earth metal perfluorooctanoate has been introduced. 1 Introduction and Background 2 Synthesis and Characterization of Rare Earth Perfluorooctanoate 2.1 Synthesis of Rare Earth Perfluorooctanoate 2.2 Characterization of Rare Earth Perfluorooctanoate 3 RE(PFO)(3) in Organic Solvent 3.1 One-Pot Mannich Reaction 3.2 Condensations of Indole with Carbonyl Compounds 3.3 One-Pot Synthesis of Benzopyran Derivatives 3.4 One-Pot Synthesis of 2-Amino-3-Cyanopyridine Derivatives 4 RE(PFO)(3) in Water 4.1 Doebner Reaction 4.2 Synthesis of Homoallylic Alcohols and Amines 5 RE(PFO)(3) under Solvent-Free Conditions 5.1 Synthesis of alpha-Aminophosphonates 5.2 One-Pot Synthesis of Substituted Pyrazoles 5.3 A Revisit to the Hantzsch Reaction 5.4 One-Pot Fluorous Biginelli Reaction 6 Summary |
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