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Concise Formal Total Synthesis of Platensimycin Mediated by a Stereoselective Autoxidation and Hydroxyl Group Directed Conjugative Reduction

  作者 MAGNUS PHILIP; RIVERA HERIBERTO; LYNCH VINCE  
  选自 期刊  Organic Letters;  卷期  2010年12-24;  页码  5677-5679  
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[摘要]The synthesis of 13, an advanced intermediate in the Nicolaou synthesis of platensimycin 1, was made from 9 by autoxidation to give 10, which was stereoselectively reduced providing 12. Finally, dehydration of 12 by heating in DMSO resulted in

 
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