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New insights into the acid mediated disproportionation of pentavalent uranyl

  作者 MOUGEL VICTOR; BISWAS BIPLAB; PECAUT JACQUES; MAZZANTI MARINELLA  
  选自 期刊  Chemical Communications;  卷期  2010年46-45;  页码  8648-8650  
  关联知识点  
 

[摘要]The reaction of benzoic acid with the uranyl(V) complex [(UO2Py5)(KI2Py2)] in pyridine leads to immediate disproportionation with formation of a hexanuclear U(IV) benzoate cluster, a bis-benzoate complex of uranyl(VI) and water.

 
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