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Pasteur's quasiracemates in 2D: chiral conflict between structurally different enantiomers induces single-handed enantiomorphism

  作者 ROTH CHRISTIAN; PASSERONE DANIELE; ERNST KARLHEINZ  
  选自 期刊  Chemical Communications;  卷期  2010年46-45;  页码  8645-8647  
  关联知识点  
 

[摘要]During two-dimensional chiral conglomerate formation of tartaric acid on the copper(110) surface, the growth of one enantiomorph is suppressed by the opposite chirality of a coadsorbed malic acid enantiomer, forming a quasi-racemic, semi-ordered mixture.

 
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