Formal total synthesis of benzylpedamide: the right half of (+)-pederin.

[摘要]：(Biomolecules and Their Synthetic Analogs) Section The right half (I) of (+)-pederin was synthesized through a convenient and efficient asym. synthesis in 14 steps with 8.3% overall yield. The key step was an iodine-induced heterocyclization to construct the pyran ring. The chiral centers were constructed sep. via asym. allylation, substrate-controlled diastereoselective reactions, and Sharpless asym. dihydroxylation.

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