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Radical Deoxygenation of Xanthates and Related Functional Groups with New Minimalist N-Heterocyclic Carbene Boranes

  作者 UENG SHAUHUA; FENSTERBANK LOUIS; LACOTE EMMANUEL; MALACRIA MAX; CURRAN DENNIS P  
  选自 期刊  Organic Letters;  卷期  2010年12-13;  页码  3002-3005  
  关联知识点  
 

[摘要]Minimalist N-heterocyclic carbene boranes 1,3-dimethylimidazol-2-ylideneborane and 2,4-dimethyl-1,2,4-triazol-3-ylideneborane are readily available and have low molecular weights. They exhibit superior performance to first-generation NHC boranes, providing improved yields in reductions of xanthates and related functional groups.

 
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