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Synthesis of Bis(diaryl)sulfones by Site-Selective Suzuki-Miyaura Reactions of 2,4 '-Bis(trifluoromethylsulfonyloxy)diphenylsulfone

  作者 ALI ASAD; KHERA RASHEED AHMAD; IBAD MUHAMMAD FAROOQ; HUSSAIN MUNAWAR; LANGER PETER  
  选自 期刊  SYNLETT;  卷期  2010年-5;  页码  731-734  
  关联知识点  
 

[摘要]The Suzuki-Miyaura reaction of the bis(triflate) of 2,4'-bis( hydroxy) diphenylsulfone with two equivalents of boronic acids gave 2,4'-bis(aryl)diphenylsulfones. The reaction with one equivalent of arylboronic acids resulted in site-selective attack onto carbon atom C-4'.

 
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